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IR vs. Raman of pri...
 
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IR vs. Raman of primary amines

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Looking at the IR and Raman spectra of two primary amines - isopropyl amine and isobutyl amine - there is approximately a 30 cm-1 difference between the IR and Raman spectra for the symmetric N-H stretch.  The Raman band is at the higher frequency - 3329 in the Raman, 3300 in the IR for isobutyl amine.  Anyone happen to know why that is?



   
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